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二氧化氮(NO2)是一种典型的大气污染物，室温下实现NO2气体的高灵敏检测具有重要实际意义。以二硫化锡(SnS2)为代表的金属硫化物表现出优异的室温响应性能。SnS2是一种具有六方结构(S-Sn-S)的n型半导体材料，具有高导电率、高表面活性、出色的电子迁移率和良好的抗氧化性能等优势，通过空位、掺杂和异质结工程等方法可有效改善其能带结构、电荷转移机制、物理吸附和表面活性，进而提升气敏性能。鉴于此，本文从SnS2晶体结构和合成方法入手，重点围绕其响应机理和性能优化方法展开讨论，系统综述了SnS2应用于电阻式NO2气体传感器的研究现状，并对其发展前景做出展望，为高性能环境气体感知材料与器件的开发提供借鉴。
Abstract：Nitrogen dioxide(NO2) is a kind of the typical representatives of air pollutants, and the detection of NO2gas at room temperature is of great practical significance. The metal sulfide represented by tin disulfide(SnS2) shows excellent room temperature response. SnS2 is a n-type semiconductor with a hexagonal structure(S-Sn-S), which has the merits of high conductivity, high surface activity, excellent electron mobility, and good oxidation resistance.The energy band structure, charge transfer mechanism, physical adsorption, and surface activity can be effectively promoted by vacancy, doping, and heterostructure engineering methods, to improve the gas-sensitive performance.In this study, the crystal structure and synthesis methods of SnS2 were analyzed, the response mechanism and performance improvement were discussed, the current research status of SnS2 in resistive NO2 gas sensors was systematically reviewed, and its development prospects were also predicted, which will provide references for the development of high-performance environmental gas sensing materials and devices.
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基本信息:
DOI：10.19370/j.cnki.cn10-1886/ts.2025.03.001
中图分类号:TP212
引用信息:
[1]涂倩,吴超狄,罗瑞等.基于二硫化锡的电阻式二氧化氮传感器研究进展[J].印刷与数字媒体技术研究,2025,No.236(03):1-12.DOI:10.19370/j.cnki.cn10-1886/ts.2025.03.001.
基金信息:
湖北省高等学校优秀中青年科技创新团队项目(No.T20220388); 大学生创新创业训练计划项目(No.202411336001); 荆楚理工学院高教研究项目(No.GJZD2401)